Question step one9. The species HdosO, HCOstep three – , HSOcuatro – and NH3 can act both as Bronsted acid and base. For each case, give the corresponding conjugate acid and base. Answer:
Question 20. (a) OH – ions (b) F – (c) H + (d) BCI3 Answer: (a) OH – ions can donate an electron pair and act as Lewis base. (b) F – ions can donate an electron pair and act as Lewis base. (a) H + ions can accept an electron pair and act as Lewis base. (b) BCl3 can accept an electron pair since Boron atom is electron deficient. It is a Lewis acid.
Question 21. Predict the acidic, basic or neutral nature of the solutions of the following salts: NaCI, KBr, NaCN, NH4NO3, NaNO2, KF. Answer: NaCN, NaNO2, KF solutions are basic, as they are salts of strong base, weak acid. NaCl, KBr solutions are neutral, as they are salts, of strong acid, strong base. NH4NO3 solution is acidic, as it is a salt of strong acid, weak base.
Concern twenty two. Ionic device away from h2o at the 310 K try dos.seven x 10 -fourteen What’s the pH off simple water at this heat? Answer:
Concern 23. This new aqueous services out of sugar cannot perform stamina while when salt chloride was added to drinking water, it performs power. Validate which statement. Answer: step 1. Glucose is actually a non electrolyte and in case it dissolves in the water, there won’t be any ionisation takes place. If there is zero 100 % free ions, it doesn’t carry out electricity.
O try acidic
dos. When salt chloride are placed into drinking water, it’s entirely ionised to provide Na ions and Cl – ions. As a result of the exposure from ions, they’ll be probability of electhcal conductance. Because ions was providers regarding electric energy.
step 3. An effective Lewis acidic are an enthusiastic electron lacking molecule and you will able to taking a set of electrons and a great Lewis foot are electron rich molecule and you will able to donating a set of electrons.
Question twenty five. The brand new salt from solid acidic and strong base doesn’t read hydrolysis. Identify. Answer: step one. In this case, neither the latest cations nor new anions experience hydrolysis. And the service remains natural.
2. Such as, on aqueous service of NaCl, their ions Na + and Cl – ions have no habit of behave with H + or OH – ions out-of liquid.
Simply because the fresh you’ll be able to situations of these impulse try NaOH and you can HCI that are totally dissociated. Because of this, there is absolutely no change in the newest concentration of W and you can OH – ions thus the answer continues to are basic.
Question step one. Describe Lowry – Bronsted concept away from acid and you can legs. Answer: step one. Based on Lowry-Bronsted idea, an acidic is described as a substance who’s a propensity to give an effective proton to some other material and feet try an effective compound who’s got a propensity to accept good proton from http://www.datingranking.net/escort-directory/lincoln/ other compound.
3. When HCI is dissolved in H2O, HCI donates a proton to H2O. Thus HCI behaves as an acid and H2O is a base. HCI + H2O \(\rightleftharpoons\) H3O + + Cl –
Question 2. Explain the reaction of water with ammonia by proton theory. Answer: 1. When ammonia dissolved in water, it accepts a proton from water. In this case, ammonia (NH3) acts as a base and H2
Classify the next kinds toward Lewis acids and you may Lewis bases and you will let you know how these can play the role of Lewis acid We Lewis base?
3. The species that remains after the donation of a proton is a base (Base1) and is called the conjugate base of Bronsted acid (Acid1). In other words, chemical species that differ only by a proton are called conjugate acid base pairs Conjugate acid – base pair